April 23, 2024

Simulation of behavioural modification effects in suspension waste pipe flows.

In nuclear facilities around the UK, waste suspension flows transport legacy radioactive material between, e.g., historic ponds and interim storage facilities as part of decontamination processes. The waste treatment programme relies heavily on the retrieval of legacy sludges, often performed using circular cross-section pipelines which transport solid-liquid suspensions over significant distances. Presently, these systems suffer […]

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April 23, 2024

Improving in situ acoustic characterisation of suspensions with machine learning methods

Waste suspension flows are encountered across the nuclear sector, and their characterisation is of great importance to the safe transport of radioactive material. A waste treatment program that has received high priority in recent years, is the retrieval of legacy waste sludge from historical ponds to safe interim storage facilities. Suspension transfer via pipeline has […]

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April 23, 2024

Modelling nanoscale radiation physics/chemistry processes in sludges

Using a combination of kinetic Monte Carlo radiation transport and (if necessary) atomistic simulation approaches, this investigator will investigate the energy transfer processes at work when brucite is irradiated in water. The description of the energy spectrum of particles thus transferred from the brucite to the water will be augmented with description of the energy […]

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April 23, 2024

Durability of magnesium silicate cements

Magnesium silicate hydrate (M-S-H) based cements are a new type of cement that exploits the strength generated when magnesium oxide is made to react with a soluble silica source to form a mostly amorphous hydrated gel of magnesium silicate (M-S-H gel). It is a perfect candidate for reducing the volume of waste from the fuel […]

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April 23, 2024

Radiation effects on wasteforms

This project will focus on determining how the degree of crystallinity would affect cracking of vitrified High Level Waste (HLW). Radiation is known to affect glass in a variety of ways, for example causing a volume change. This volume change can induce strain which can lead to cracking. Historic work on active glass showed that […]

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April 23, 2024

Characterisation of thermal treatment products

A programme of synthesis of a range of model (lab-scale) thermally treated simulant waste materials will be initiated with the addition of active (e.g. U, Th) or inactive (e.g. Cs, Ce for Pu etc.) radionuclide surrogates. We will liaise with NNL to also obtain products of full-scale Geomelt trials (active or inactive) for appropriate waste […]

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April 23, 2024

Process monitoring of thermal treatment of nuclear wastes

A considerable proportion of the UK’s LLW and ILW radioactive waste inventories arise in a range of physical and chemical forms with varying degrees of radioactive / toxic hazard. They include PCM, IEX resins and decommissioning wastes such as concrete, bricks, sludges and contaminated soils. These wastes are considered unsuitable for treatment using existing vitrification […]

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April 23, 2024

Understanding glass melt chemistry in thermal treatment of nuclear waste

This project is intended to develop a deeper understanding of how glass chemistry can be used to maximise waste incorporation while minimising volatilisation. Specific aims are to understand the waste incorporation reactions and radionuclide incorporation mechanisms for a variety of representative wastes. These aims will be addressed by undertaking 1) investigations of quenched melts produced […]

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